Spectrophotometric determination of aluminium and indium with 2,2',3,4-tetrahydroxy-3',5'-disulphoazobenzene.
Identifieur interne : 001C53 ( Main/Exploration ); précédent : 001C52; suivant : 001C54Spectrophotometric determination of aluminium and indium with 2,2',3,4-tetrahydroxy-3',5'-disulphoazobenzene.
Auteurs : RBID : pubmed:18783882English descriptors
- KwdEn :
- MESH :
- chemical , analysis : Aluminum, Indium, Water Pollutants, Chemical.
- chemical : Benzene Derivatives.
- analysis : Fresh Water.
- methods : Spectrophotometry.
Abstract
2,2',3,4-Tetrahydroxy-3',5'-disulphoazobenzene (tetrahydroxyazon 2S) has been synthesized for the first time. This reagent has been used for the spectrophotometric determination of aluminium and indium ions. The method is very sensitive and selective for the direct determination of aluminium and indium. The optimum pH and absorbance of complexes formed of tetrahydroxyazon 2S with aluminium and indium are 5; 500 nm and 495 nm for Al and In, respectively. The system obeys Beer's law at 0.05-1.6 microg mL(-1) of aluminium and 0.06-2.1 microg mL(-1) of indium concentration. The molar absorptivity is 6.42 x 10(4)L mol(-1)cm(-1) for aluminium and 7.70 x 10(4)L mol(-1)cm(-1) for indium. The molar compositions of the complexes are 1:1 at optimum conditions. Alkaline and alkaline earth elements, halogens, thiourea, ascorbic acid, Cd(II), Pb(II), Mn(II), Zn(II), Co(II), Ni(II), Cr(III), Bi(III), La(III), Si(IV) do not interfere this method. The method can be applied to the direct spectrophotometric determination of trace amounts of aluminium in steel, alloys, waste water, river waters, spring water and ground water. The method was also successfully applied to the indium determination in artificial mixture.
DOI: 10.1016/j.jhazmat.2008.07.055
PubMed: 18783882
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Spectrophotometric determination of aluminium and indium with 2,2',3,4-tetrahydroxy-3',5'-disulphoazobenzene.</title><author><name sortKey="Huseyinli, A A" uniqKey="Huseyinli A">A A Huseyinli</name><affiliation><nlm:affiliation>Baku State University, Faculty of Chemistry, Baku 1148, Azerbaijan. ahuseyinli@yahoo.com</nlm:affiliation><country wicri:rule="url">Colombie</country></affiliation></author><author><name sortKey="Alieva, R" uniqKey="Alieva R">R Alieva</name></author><author><name sortKey="Haciyeva, S" uniqKey="Haciyeva S">S Haciyeva</name></author><author><name sortKey="G Ray, T" uniqKey="G Ray T">T Güray</name></author></titleStmt><publicationStmt><date when="2009">2009</date><idno type="doi">10.1016/j.jhazmat.2008.07.055</idno><idno type="RBID">pubmed:18783882</idno><idno type="pmid">18783882</idno><idno type="wicri:Area/Main/Corpus">002240</idno><idno type="wicri:Area/Main/Curation">002240</idno><idno type="wicri:Area/Main/Exploration">001C53</idno></publicationStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Aluminum (analysis)</term><term>Benzene Derivatives</term><term>Fresh Water (analysis)</term><term>Indium (analysis)</term><term>Spectrophotometry (methods)</term><term>Water Pollutants, Chemical (analysis)</term></keywords><keywords scheme="MESH" type="chemical" qualifier="analysis" xml:lang="en"><term>Aluminum</term><term>Indium</term><term>Water Pollutants, Chemical</term></keywords><keywords scheme="MESH" type="chemical" xml:lang="en"><term>Benzene Derivatives</term></keywords><keywords scheme="MESH" qualifier="analysis" xml:lang="en"><term>Fresh Water</term></keywords><keywords scheme="MESH" qualifier="methods" xml:lang="en"><term>Spectrophotometry</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">2,2',3,4-Tetrahydroxy-3',5'-disulphoazobenzene (tetrahydroxyazon 2S) has been synthesized for the first time. This reagent has been used for the spectrophotometric determination of aluminium and indium ions. The method is very sensitive and selective for the direct determination of aluminium and indium. The optimum pH and absorbance of complexes formed of tetrahydroxyazon 2S with aluminium and indium are 5; 500 nm and 495 nm for Al and In, respectively. The system obeys Beer's law at 0.05-1.6 microg mL(-1) of aluminium and 0.06-2.1 microg mL(-1) of indium concentration. The molar absorptivity is 6.42 x 10(4)L mol(-1)cm(-1) for aluminium and 7.70 x 10(4)L mol(-1)cm(-1) for indium. The molar compositions of the complexes are 1:1 at optimum conditions. Alkaline and alkaline earth elements, halogens, thiourea, ascorbic acid, Cd(II), Pb(II), Mn(II), Zn(II), Co(II), Ni(II), Cr(III), Bi(III), La(III), Si(IV) do not interfere this method. The method can be applied to the direct spectrophotometric determination of trace amounts of aluminium in steel, alloys, waste water, river waters, spring water and ground water. The method was also successfully applied to the indium determination in artificial mixture.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="MEDLINE"><PMID Version="1">18783882</PMID><DateCreated><Year>2009</Year><Month>02</Month><Day>16</Day></DateCreated><DateCompleted><Year>2009</Year><Month>04</Month><Day>13</Day></DateCompleted><DateRevised><Year>2013</Year><Month>11</Month><Day>21</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1873-3336</ISSN><JournalIssue CitedMedium="Internet"><Volume>163</Volume><Issue>2-3</Issue><PubDate><Year>2009</Year><Month>Apr</Month><Day>30</Day></PubDate></JournalIssue><Title>Journal of hazardous materials</Title><ISOAbbreviation>J. Hazard. Mater.</ISOAbbreviation></Journal><ArticleTitle>Spectrophotometric determination of aluminium and indium with 2,2',3,4-tetrahydroxy-3',5'-disulphoazobenzene.</ArticleTitle><Pagination><MedlinePgn>1001-7</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1016/j.jhazmat.2008.07.055</ELocationID><Abstract><AbstractText>2,2',3,4-Tetrahydroxy-3',5'-disulphoazobenzene (tetrahydroxyazon 2S) has been synthesized for the first time. This reagent has been used for the spectrophotometric determination of aluminium and indium ions. The method is very sensitive and selective for the direct determination of aluminium and indium. The optimum pH and absorbance of complexes formed of tetrahydroxyazon 2S with aluminium and indium are 5; 500 nm and 495 nm for Al and In, respectively. The system obeys Beer's law at 0.05-1.6 microg mL(-1) of aluminium and 0.06-2.1 microg mL(-1) of indium concentration. The molar absorptivity is 6.42 x 10(4)L mol(-1)cm(-1) for aluminium and 7.70 x 10(4)L mol(-1)cm(-1) for indium. The molar compositions of the complexes are 1:1 at optimum conditions. Alkaline and alkaline earth elements, halogens, thiourea, ascorbic acid, Cd(II), Pb(II), Mn(II), Zn(II), Co(II), Ni(II), Cr(III), Bi(III), La(III), Si(IV) do not interfere this method. The method can be applied to the direct spectrophotometric determination of trace amounts of aluminium in steel, alloys, waste water, river waters, spring water and ground water. The method was also successfully applied to the indium determination in artificial mixture.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Huseyinli</LastName><ForeName>A A</ForeName><Initials>AA</Initials><Affiliation>Baku State University, Faculty of Chemistry, Baku 1148, Azerbaijan. ahuseyinli@yahoo.com</Affiliation></Author><Author ValidYN="Y"><LastName>Alieva</LastName><ForeName>R</ForeName><Initials>R</Initials></Author><Author ValidYN="Y"><LastName>Haciyeva</LastName><ForeName>S</ForeName><Initials>S</Initials></Author><Author ValidYN="Y"><LastName>Güray</LastName><ForeName>T</ForeName><Initials>T</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType>Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2008</Year><Month>07</Month><Day>23</Day></ArticleDate></Article><MedlineJournalInfo><Country>Netherlands</Country><MedlineTA>J Hazard Mater</MedlineTA><NlmUniqueID>9422688</NlmUniqueID><ISSNLinking>0304-3894</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Benzene Derivatives</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Water Pollutants, Chemical</NameOfSubstance></Chemical><Chemical><RegistryNumber>045A6V3VFX</RegistryNumber><NameOfSubstance>Indium</NameOfSubstance></Chemical><Chemical><RegistryNumber>CPD4NFA903</RegistryNumber><NameOfSubstance>Aluminum</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName MajorTopicYN="N">Aluminum</DescriptorName><QualifierName MajorTopicYN="Y">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Benzene Derivatives</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Fresh Water</DescriptorName><QualifierName MajorTopicYN="N">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Indium</DescriptorName><QualifierName MajorTopicYN="Y">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Spectrophotometry</DescriptorName><QualifierName MajorTopicYN="N">methods</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Water Pollutants, Chemical</DescriptorName><QualifierName MajorTopicYN="Y">analysis</QualifierName></MeshHeading></MeshHeadingList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2007</Year><Month>12</Month><Day>25</Day></PubMedPubDate><PubMedPubDate PubStatus="revised"><Year>2008</Year><Month>6</Month><Day>2</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2008</Year><Month>7</Month><Day>14</Day></PubMedPubDate><PubMedPubDate PubStatus="aheadofprint"><Year>2008</Year><Month>7</Month><Day>23</Day></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2008</Year><Month>9</Month><Day>12</Day><Hour>9</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2009</Year><Month>4</Month><Day>14</Day><Hour>9</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2008</Year><Month>9</Month><Day>12</Day><Hour>9</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pii">S0304-3894(08)01088-1</ArticleId><ArticleId IdType="doi">10.1016/j.jhazmat.2008.07.055</ArticleId><ArticleId IdType="pubmed">18783882</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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